Simultaneous DBO removal and nitrification in WWTP
Published on by Felipe Gonzalez Gonzalez, Consultant on Sanitary Engineering in Case Studies
I want to know the general requirements for nitrification and DBO removal in an aerobic reactor in a wastewater treatment plant. How common is it for having both processes in the same reactor? what are typical hydraulic retention times for industrial wastewaters? what should the sludge age be so that nitrifying bacteria can work efficiently? Would it be the same requirements on an normal activated-sludge aerobic reactor and a MBBR aerobic reactor?
Thanks so much in advance
Taxonomy
- Industrial Wastewater Treatment
- Industrial Water Treatment
- Wastewater Treatment
- Wastewater Treatment Plant Design
- Water & Wastewater Treatment
- Water Treatment Plant Design
- Nitrogen
- Associate Professor in Water Chemistry and wastewater treatment
- MBBR for Water Treatment
5 Answers
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I fully agree with Rice's answer. In MBBR you have to design system in IFAS configuration because kinetics is very differente. Regards.
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n Rice's answer is very good, but add a few ratios to the mix. I would multiply the BOD rate 1.5 for DO required to offset alpha and beta values, and for Nitrification use a factor of 4.5 times the concentration of N-NH3 for maintaining alkalinity. If there is uncertainty about presence of Nitrifying bacteria, add a small incubator and feed "live" cultures into the basin to ensure sufficient CFUs of Nitrifiers are present.
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To expound on Andre Visser's comments -
1. Unless the wastewater is very cold, nitrification kinetics in activated sludge systems tends to be pretty fast. Conventional systems typically have an HRT around 3-5 hours, while extended aeration systems can have an HRT up to 35 or 40 hours. But that long HRT in extended aeration time is designed to resist washout events and help stabilize shock loads, not to give enough contact time for nitrification. The contactor in a contact-stabilization system can have an HRT as low as 30 minutes some times. Or, think of an SBR, which can have relatively short aeration cycles.
2. WEF's MOP 8 has a table of common inhibitors if you think you have something inhibiting nitrification. There's other issues with industrial wastewaters that are relatively common, such as ammonia toxicity in landfill applications.
3. There's a few different models for minimum SRT for nitrification - you can use a monod-type equation to figure out it. One reference you can look at is the US EPA's 1993 Nitrogen Control Manual. But generally you want no less than 6 days SRT at 10C as the absolute minimum. Below that you'll likely get unstable nitrification and will see a lot of NO2 in your effluent instead of NO3 due to AOB/NOB metabolism dynamics.
a. Note that this ignores the impact of pH, DO concentration, etc - but there's corrections for those too.
b. Nitrifiers have a lower specific growth rate than heterotrophs, so this is almost always your limiting factor for SRT.
c. As a rule of thumb, I usually define my operating SRT as no less than twice the design SRT.
d. Temperature is a really, really important factor. The growth rate of your AOB's (eg Nitrosonomas) tends to asymptote to zero below 6C.
4. The vast majority of activated sludge processes are doing BOD treatment and nitrification in the same basin. You can't tell your system to stop nitrifying short of reducing the SRT to near-zero.
5. You do need to remove most of the BOD prior to starting nitrification because heterotrophs will outcompete autotrophs (typically 90%+ of your biomass is heterotrophic) However, it doesn't need to be 100%. Nitrification will start before complete BOD treatment is achieved. I've heard that it typically starts around a TKN/BOD ratio of like 1/3, but I'd have to dig up a source on that.
6. I'm not an expert on MBBR's, so I'll leave that comment to others. I will point out that autotrophs prefer an attached growth mechanism, which an MBBR obviously encourages.
1 Comment
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Hi Alan,
Appreciate your time for answering my doubts. This info is very useful, I'm now on the safe side regarding one design of a WWTP I carried out, as well as the operation. Thanks again!
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Hi Felipe, Biological oxygen demand removal and nitrification is normally done in the same basin, although the biological oxygen demand will essentially be satisfied first before nitrification will commence. If the hydraulic retention is too short, all the BOD may not be removed and nitrification will not happen (typical hydraulic retention would be in the order of 20 hours for domestic sewage depending on process configuration). Nitrification is subject to possible inhibition by some pollutants and is sensitive to temperature. Low temperatures will required a longer sludge age. With temperatures in the region of 15C to 25C typical sludge age could be in the order of 6 -12 days (high temp) to 12-20 days (low temp) depending on other nitrification inhibitors (inhibition more probable in industrial type effluents), MBBR should assist nitrification due to the fact that a nitrifying culture could establish on the media and counteract lack of nitrification due to short sludge ages in conventional mixed liquor suspended solids activated sludge units,
1 Comment
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Hi Andre, everything was quite clear from your explanation, i appreciate your help very much! Kind regards.
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without detail water analysis it is not proper to give predictions water treatment need basic informations to work on.