The first thing to look at ...

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The first thing to look at is a BOD vs the COD; they do not necessarily follow each other.  It depends upon what the waste is composed of.  For example a high BOD with a low COD with a food produce vs a lower BOD and an high COD for a product from tannins from a lumber operation.   COD may have to be broken with an oxidizer such as Hydrogen peroxide, or chlorine.  A high BOD can be easily broken with bacteria cultures  - such as strains of Bacillus - along with air injection.

However, the pH of 8.1 is OK, but on the high side of 8.2 for the best bacteria digestion.  Slightly lowered pH with a little acid can greatly improve bacteria digestion;  a 7.5 would be a great point to shoot for.