How to Treat Electroplating Waste at Source?
Published on by Mahesh Gadekar, Founder and Chief Executive at GeoEnviroVision in Technology
I am interested in reducing high levels of total dissolved solids (TDS) from electroplating waste. Is there a method which does not cost too much, other than dilution, to reduce TDS?
How can we separate the metals from waste water? What is the best method to recover them efficiently?
Taxonomy
- Solid Waste Management
- Treatment
- Solid Waste Treatment
- Heavy Metal Removal
- Waste Water Treatments
- Technology
- Wastewater Treatment
- Element Separation By Vapor
- Inorganic Chemicals
- Metals
- Waste Disposal
- Solid Waste Management
- Waste Water Treatment
- Waste Management
- Total Dissolved Solids (TDS)
18 Answers
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With vacuum evaporation you can reach very high solid concentration and great amount of water saved. If Electrical consumption per liter seems higher in comparison to other filtration system, you have to consider the extremely different time and cost necessary for spare parts and maintenance stop.
There are no parts which required periodical stop for substituton, or expensive cleaning procedure and chemicals. Typical electrical consumption is 100-130 Wh/liter but it can be reduce to only 10-20 Wh/liter according to effluent amount, availability of hot-cold water in your factory.With more details of your request we can suggest proper solution.
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Usually membrane technology can help to resolve this problem. If NF or RO needs to be used, maybe with UF as pre-treatment, depends on the kind of components in this wastewater. So as first, beside the specification of the volume to be treated, a reliable analysis is necessary that needs to address all dissolved components, pH, temperature and electrical conductivity. Based on this information the solution has to be developed step by step, maybe leading to a zero liquid discharge (ZLD) process that allows to recover valuable components and clean water contributing thus to create an added value and avoid further pollution.
Best regards
Dr. Thomas Peters
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You may try Phytoremediation methods,
First run the waste water through PH stablisation tanks.
Next run this over a bioswale trench using concrete or HDPE liners to prevent leaching.
There should be about 1000 mm gravel base and about 300-500 mm rootzone.
Collect the treated wastewater and run the same in another bioswale.
Repeat the treatment in third and fourth bioswale.
You may use locally available fast growing plants that have fibrous roots and some tubers.
Collect all the biomass and send it to a biogas chamber.
Collect the sludge and incinerate.
You shall be able to collect most of the metal lost and prevent the enviornmental damage.
Hope you have the land and workforce available at low cost in your area.
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In electroplating industry the waste contains mainly metals and some undesired anions. Metals can be precipetated in an alkaline environment as all metal hydroxides are insoluble except the alkali group. If you've got cyanides then you need to oxidise them to cyanates which are harmless using NaClO at a pH around 10 and an ORP around 900mv. This is the basic method but it does depend on the concentration of the various pollutants in your waste water. If you've got a detailed analysis it would help a great deal.
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We have process equipment which contains all process contact in glass with only small parts made of high quality stainless steel. We process contaminated water to distilled water and dry salt/mineral/metal content. Ours may fit your special situation exactly.
1 Comment
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See our website at www.suns-river.com
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Depending on your location and volume of effluent, it may be cheaper to have it sent to a CETP and meet statutory compliance
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Hi Mahesh!
Practice of the resource efficient cleaner production (RECP) approach is proven to reduce the quantity as well as the toxicity of waste water in electroplating processes. Check out our project website www.acidloop.in wherein we report the approach, case studies and results from a EU SWITCH Asia project that ran from 2012 to 2016 at 6 locations in India - covering more than 100 metal finishing industries. Please reach out to me if you need more information.
Best,
Rajat
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hi Mahesh, what is the pH of the electroplating wastewater. membrane technology can be used to reduce the TDS , directly with minimum pretreatment.
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hi Mahesh, what is the pH of the electroplating wastewater. membrane technology can be used to reduce the TDS , directly with minimum pretreatment.
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hi Mahesh, what is the pH of the electroplating wastewater. membrane technology can be used to reduce the TDS , directly with minimum pretreatment.
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Dear Mahesh,
Electroplating industry consumes and discharge large volumes of wastewater.Use of various chemicals and metal salt creates pollution problems.Major pollution caused by rinse water, spray losses and solution dumping and leakages. Valuable metals and cyanide along with different chemicals used arelost in wastewater. The amount may be 2-20% of the chemicals used. Thereforegreater efforts shall be required to reduce the pollution problems. The effluent concentration depends on various factors such as surface area, shape of article thickness of solution, speed of removal, drain time etc.
Following method to minimise electroplating waste,
- COAGULATION AND PRECIPITATION
- Treatment with ferrous sulphate
- Treatment with sulphur dioxide
- Treatment with sulphuric acid
- Treatment with barium chromate
- Alkaline chlorination treatment
- Electrolytic decomposition method
- Evaporation
- Treatment with ozone
The applicability of all these techniques depends on the type and scale ofoperationAll these methods of recovery are directly related to economy ofthe system in certain cases it is economical to treat the effluent rather than try to recover the metal.
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You must isolate the process and not allow the electroplating waste to mix with water/ liquids of other processes. Once you isolate the batch process waste or effluent, opt for guaranteed specialised treatment with recovery of metals and lowering of TDS levels.. then only water can be recirculated or disposed off with other waste waters for usual treatment
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You can use our Capacitivie Deionization system to concentrate the nickel rinse water, feed back to plating bath, and use the clean water generated to supplement rinse water. www.atlantis-water.com
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The only practical way to actually reduce TDS is reverse osmosis.
With certain plating rinses (e.g. nickel) it is possible to recover it and put it back into the bath.
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Physical/chemical treatment of plating wastes is a fairly common way to treat. Depending on they metals you want to remove, the pH will need to be monitored. ORP will be needed to feed in precipitant aids such as DTC or Sulfide. A polymer for building floc and a filter for solid removal will be needed as well. Generally speaking, we can get metals down from over a 1000ppm to under 1ppm with this process.
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Yes, please contact us at servicesenvirochem@gmail.com
Will provide techno-commercial details of the same.