Removal of Nickel

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Hi,

I am searching information about removal of nickel during the softening with lime or soda of an underground water.

What is the maximum percentage removed? the best pH value?

Thanks for your help

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10 Answers

  2. Very good comments!

    On the way, sometimes you could need use an oxidant (O2, or ozone as faster oxidant) before the pH incress to have a better removal.

    Regards,

  3. thank you all for your answers which will be very useful to me

  4. Bonjour Hélène

    As Gerard Van Gils says (he shows you a very useful graph), If you reach pH=9, you will remove Ni until you get about 3.5 mg/L in solution; if pH=10, then remaining Ni in solution is about 0.13 mg/L, and so on. 

    You can add NaOH, Ca(OH)2, Mg(OH)2... tot get those pH, but if you don't want to use chemicals you can remove Ni (and other metals simultaneously) using OneWater system (www.onewatertech.com).

  5. I do not have the pH in front of me, but I believe it is much higher than 8.5 to 9. to get free OH alkalinity you need to be above a pH of 10.5; for the metal precipitation..  The first course in Qualatative Analysis taught us that by raising the pH will precipitate a lot of things, including metals; not to be confused with the precipitation of carbonates and bicarbonates as found in the soda ash & lime  (calcium oxide) process.  Depending upon your requirements calcium oxide, calcium hydroxide, sodium hydroxide or potassium hydroxide may be used.  It depends upon your process and the cost one can tolerate to get the precipitation you want.;  you just need to get the pH up to 10.5 or higher for a free OH radical to be present for metal precipitation.   

    I am using the pH elevation to drop most of the nickel, copper, silver and gold out of the rinse water for a plating operation.  The first step of raising the pH is kinda simple.  The final removal of nickel is done with a product we developed called Nickout.  It pulls the last amount of precious metals down so that theymeet the requirements for discharged.  After the process we bring the pH back down to about 9 for discharge to keep the goveernment  happy.

    The precipitated precious mental are then filtered, dried and sold. They get about $200K for every filtered sludge that is sent in.  We comfirm the final discharge of the waste water by ICP analysis.  We get to sell them Nickout, and do the confirming analysis for the waste water regulations.  If you need some nickout solution, to remove a low ppm  (below 1 ppm) of these mental, contact me at wh@bluevalleylabs.com.

  6. Hi. It relates to the amount of nickel and you flow rate. If you alter the pH to 8.5-9, thd nickel will be removed in the form of hydroxide and normaly, around 50% of hardness will be setteled as well. The amount of nickel can be removed between 95-98%.

    The remainig Ni, can be removed by special ion-exchange resins from PUROLITE company.

    Good luck

  7. we gave an easy process. What is your volume  ?

  9. Hydroxide precipitation of Nickel with proper solids removal will result in a residual of approximately 0.3-0.4 mg/l at pH 10.

    Magnesium Hydroxide will generate less sludge than Calcium Lime.